Class Outline for Thursday April 21, 2005

  • Warm Up/Admin

  • Bridge Project Winners
  • Bridge Homework
  • Web site/Newsgroup
  • Reading for this week
    • review pages 398-400

    • acids, bases & salts p. 401-406

    • Salts

  • Vocabulary
  • Acids, acidity, bases, basicity, pH, indicators, corrosive, ions, salts, hydroxide, Salts

  • Finish LaB

  • Baseball

    • Why?

    • Who Plays

    • Rules

    • Questions

The Operational Definition of Acids and Bases

The fact that water dissociates to form H+ and OH- ions in a reversible reaction is the basis for an operational definition of acids and bases that is more powerful than the definitions proposed by Arrhenius. In an operational sense, an acid is any substance that increases the concentration of the H+ ion when it dissolves in water. A base is any substance that increases the concentration of the OH- ion when it dissolves in water.

These definitions tie the theory of acids and bases to a simple laboratory test for acids and bases. To decide whether a compound is an acid or a base we dissolve it in water and test the solution to see whether the H+ or OH- ion concentration has increased.

How would you know if it's aN ACID

  • some metal hydrides

    • HI, LiH, NaH, KH, MgH2, Cao
  • some metal oxides

    • Li2O, Na2O, K2O, MgO, CaO
  • some metal hydroxides

    • LiOH, NAOH, KOH, CA(OH)2, Ba(OH)2

How would you know if it's a BASE

  • some non-metal hydrides

    • HF, HCl, HBr, HCN,HSCN, H2S
  • some non-metal oxides

    • CO2, SO3, SO2, NO2,NO2,P4O10
  • non-metal hydroxides

    • HOCl, HONO2, O2S(OH)2, OP(OH)3
  1. Try it on the lab exercise

     

    Common Name

    Scientific Name

    Formula

    metal

    non-metal

    hydride

    oxide

    hydroxide

    Acid or Base

     

     

     

     

     

     

     

     

     

    a.vinegar

    Acetic Acid

     

    N

     

     

     

     

     

    b. sugar

    Glucose

     

     

     

     

     

     

     

    c. ammonia e.

    Ammonia

    NH4OH

     

     

     

     

     

     

    d. Sode

    Carbonic Acid

    H2CO3

    N

     

     

     

     

     

    e.

    sodium hydroxide

     NaOH

    Y

     

     

     

     

     

    f.  Water

    Agua

    H2O or HOH

    N

     

     

     

     

     

    g. Breath

    Carbon Dioxide

    CO2

    N

     

     

     

     

     

    h. Milk

    Calcium Carbonate

    CaCO3, Ca(OH)2

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

  2. The pH Scale

  • 7 is pH of pure water
  • > 7 greater basicity
  • <7 greater acidity

Acid and Bases Challenge

 

Harry celebrated a little too much on New Years Eve last year and woke up with a very upset stomach. He had committed to go to his mother-in-laws with his wife to watch football and have dinner.

When he got there he was obviously not feeling well. He got all sorts of advice from friends and family about how to ‘cure’ his problem. The only ones that he had available at that time were:

  1. Milk
  2. Menudo
  3. Alka-Seltzer (soda water)
  4. Plain Water
  5. Orange Juice
  6. Flat Beer

CAN YOU HELP HARRY DECIDE?

Assume that his problem is that his stomach has become too acidic.

To make him feel better it must be made more neutral. Which subtance does this best?

Use slightly diluted vinegar to model his stomache fluids

There is plenty of Red Cabbage there

Design an experiment that could tell Harry which one of the 6 ‘cures’ above would be the best for his problem.

 

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Copyright © 2005 -  S. B. EglI